姓名：夏子豪

所在系室：应用化学

研究方向：可见光催化的自由基反应研究及其应用；绿色化学

邮箱：xiazihao@bua.edu.cn

教育经历：2015-2020 中国科学院化学研究所 博士

2011-2015 广西大学 学士

工作经历：2020.10-至今 北京农学院

代表作：

Zi-Hao Xia, Chun-Lin Zhang, Zhong-Hua Gao* and Song Ye*. Switchable Decarboxylative Heck-type Reaction and Oxo-alkylation of Styrenes with N-Hydroxyphthalimide Esters under Photocatalysis. Org. Lett. 2018, 20, 3496.

Zi-Hao Xia, Zhong-Hua Gao, Lei Dai and Song Ye*. Visible Light Promoted Oxo -Difluoroalkylation of Alkenes with DMSO as the Oxidant. J. Org. Chem. 2019, 84, 7388.

Zi-Hao Xia, Lei Dai, Zhong-Hua Gao and Song Ye*. N-Heterocyclic Carbene/Photo-Cocatalyzed Oxidative Smiles Rearrangement: Synthesis of Aryl Salicylates from O-Aryl Salicylaldehydes. Chem. Commun., 2020, 56, 1525.

主讲课程：有机化学，有机化学实验，普通化学实验

获奖荣誉：

第二届国润杯大学生环保科普大赛三等奖 （指导教师）

第13届北京市大学生化学实验竞赛综合组一等奖（指导教师）

Curriculum Vitae

I. Personal information

Zihao Xia, Ph.D (Institute of Chemistry, Chinese Academy of Sciences), the College of Bioscience and Resources Environment, Beijing University of Agriculture (BUA).

II. Research interests

Focused on green organic synthesis and post-modification of functional molecules, with a commitment to developing novel agrochemicals, including heterocyclic compounds with significant biological activity, for applications in insecticides, herbicides, fungicides, and plant growth regulators. The research emphasizes green chemistry principles, utilizing radical chemistry and visible-light photocatalysis to achieve greener alternatives to traditional synthetic reactions and streamline complex processes.

III. Research Projects

1. Youth Foundation of Beijing University of Agriculture (QNKJ202102).

2. R&D Program of Beijing Municipal Education Commission (KM202210020007).

3. Research and Innovation Ability Improvement Project for Young Teachers of Beijing University of Agriculture (QJKC2022014).

4. Science and Technology innovation support program of Beijing University of 252 Agriculture (BUA-HHXD2023008).

IV. Representative papers

1. Self-Catalyzed, Visible-Light-Induced Selective C3−H Aroylation of Quinoxalin-2(1H)‑ones with Arylaldehydes by Air as an Oxidant. J. Org. Chem. 2024, 89, 7233. (Corresponding author)

2. Novel quinoxalinone-1,2,3-triazole derivatives as potential antifungal agents for plant anthrax disease: Design, synthesis, antifungal activity and SAR study. Advanced Agrochem. 2024, 3, 222. (Corresponding author)

3. Metal-Free Synthesis of α-Iminonitriles via Visible Light Photoredox Catalysis. Asian J. Org. Chem. 10.1002/ajoc.202300247. (Corresponding author)

4. Transition-Metal-Free Multicomponent Reaction of Quinoxalinones with Alkenes and Zhdankin Reagent through Photoredox Catalysis, Eur. J. Org. Chem., 2023, 26, e202201125. (Corresponding author).

5. Self-photocatalyzed three-component radical cascade reaction of quinoxalinones, simple alkenes and zhdankin reagent. Mol.catal. 2024, 557, 113981. (Corresponding author).

6. Oleanane-Type Triterpene Conjugates with 1H-1,2,3-Triazole Possessing of Fungicidal Activity. Molecules, 2022, 27, 4928. (Corresponding author).

7. Saccharin Catalyzed Multicomponent Cascade Reactions for the Synthesis of 1,2,3,4,6-Pentasubstituted Piperidines. J. Heterocycl. Chem. 2023, 10.1002/jhet.4628. (First author).

8. N-Heterocyclic carbene/photo-cocatalyzed oxidative Smiles rearrangement: synthesis of aryl salicylates from O-aryl salicylaldehydes Chem. Commun., 2020, 56, 1525. (First author).

9. Visible-Light-Promoted Oxo-difluoroalkylation of Alkenes with DMSO as the Oxidant. J. Org. Chem. 2019, 84, 7388. (First author).

10. Switchable Decarboxylative Heck-Type Reaction and Oxo-alkylation of Styrenes with N-Hydroxyphthalimide Esters under Photocatalysis. Org. Lett. 2018, 20, 3496. (First author).

V. Contact information

Postal address: College of Animal Science and Technology, Beijing University of Agriculture, No. 7, Beinong Road, Huilongguan, Changping, Beijing, 102206

Contact number: 010-80728307

Email: xiazihao@bua.edu.cn